Solid Polymer Electrolytes – Fundamentals and Technological Applications

2.2 Poly(ethylene imine).
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<br /> 2.3 Thia–alkanes.
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<br /> References.
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<br /> Chapter 3. The Interaction Between Polymer and Salt.
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<br /> 3.1 Ion Solvation by the Polymer.
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<br /> 3.2. Hard–Soft Acid–Base Principle.
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<br /> 3.3. Artions.
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<br /> 3.4. Complex Formation.
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<br /> References.
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<br /> Chapter 4. Structure and Morphology.
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<br /> 4.1 Crystalline Phases in Polymers.
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<br /> 4.2 Preparation of Polymer Electrolyte Films.
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<br /> 4.3 Solvent Deposited and Melt Recrystallized Films.
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<br /> 4.4 Solvent Effects on Morphology.
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<br /> 4.5 Trace Impurities.
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<br /> 4.6 Intercrystalline Amorphous Phases.
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<br /> 4.7 Polymer Electrolyte Structural Determination by EXAFS.
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<br /> 4.8 Phase Diagrams.
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<br /> 4.8.1 Thiocyanates of Monovalent Cations.
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<br /> 4.8.2 Halide Systems.
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<br /> 4.8.3 Tetraphenyl Borate Systems.
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<br /> 4.8.4 Halogen–Containing Complex Anionic Systems.
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<br /> 4.8.5 Perchlorate Systems.
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<br /> 4.8.6 Trifluoromethanesulfonate Systems.
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<br /> 4.9 Mesogenic PEO–Salt Systems.
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<br /> References.
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<br /> Chapter 5. Aspects of Conductivity in Polymer Electrolytes.
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<br /> 5.1 Total Direct–Current Conductivity.
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<br /> 5.1.1 Crystallinity in Polymer Electrolytes.
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<br /> 5.1.2 Salt Concentration.
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<br /> 5.2 Pressure Dependence of the Conductivity.
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<br /> 5.3 Mixed Salt Systems.
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<br /> 5.4 Mixed Conductors.
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<br /> References.
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<br /> Chapter 6. Polymer Electrolyte Architecture.
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<br /> 6.1 Non–Ether–Based Polymer Electrolytes.
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<br /> 6.2 Amorphous Polyether–Based Polymer Architecture.
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<br /> 6.3 Enhanced Chain Flexibility.
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<br /> 6.4 Mechanical Stability.
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<br /> 6.4.1 Networks.
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<br /> 6.4.2 Comb–Branched Copolymers.
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<br /> 6.4.3 Block Copolymers.
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<br /> 6.4.4 Random Polyethers.
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<br /> 6.5 Blends.
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<br /> 6.6 Single–Ion Conductors.
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<br /> 6.7 Salts.
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<br /> References.
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<br /> Chapter 7. Further Developments in Polymer Electrolyte Materials.
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<br /> 7.1 Proton Conductors.
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<br /> 7.1.1 Polyethers.
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<br /> 7.1.2 Polyamides.
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<br /> 7.1.3 Poly(acrylic acid).
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<br /> 7.1.4 Polyamines.
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<br /> 7.1.5 Poly(vinyl alcohol).
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<br /> 7.2 Ormocers.
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<br /> 7.2.1 The Sol–Gel Process.
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<br /> 7.2.2 Ormolytes.
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<br /> 7.3 Multivalent Cation–Based Polymer Electrolytes.
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<br /> 7.3.1 Preparation of Materials.
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<br /> 7.3.2 Physical Properties.
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<br /> 7.3.2.1 Alkaline Earth Metal Cations.
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<br /> 7.3.2.2 Zinc(II).
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<br /> 7.3.2.3 Cadmium(II).
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<br /> 7.3.2.4 Lead(II).
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<br /> 7.3.2.5 Cobalt(II), Nickel(II), and Manganese(II).
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<br /> 7.3.2.6 Mercury(II).
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<br /> 7.3.2.7 Copper(II).
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<br /> 7.3.2.8 Trivalent Cation–Containing Electrolytes.
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<br /> References.
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<br /> Chapter 8. Transport Properties: Effects of Dynamic Disorder.
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<br /> 8.1 Macroscopic Models.
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<br /> 8.2 Microscopic Approach.
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<br /> 8.3 Experimental Techniques Relating to Microscopic Dynamic Properties.
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<br /> 8.3.1 Brillouin Scattering.
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<br /> 8.3.2 Dielectric Relaxation.
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<br /> 8.3.3 Nuclear Magnetic Resonance Spectroscopy.
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<br /> 8.3.4 Quasi–elastic Neutron Scattering.
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<br /> References.
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<br /> Chapter 9. Transport Properties: Ionic Species and Mobility.
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<br /> 9.1 Ion–Ion Interactions.
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<br /> 9.2 Spectroscopic Studies.
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<br /> 9.2.1 General Interpretation of Spectral Data.
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<br /> 9.3 Transference Numbers.
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<br /> 9.3.1 Transport Numbers from Diffusion Coefficient Determinations.
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<br /> 9.3.1.1 Radiotracer Studies.
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<br /> 9.3.1.2 Pulsed Field Gradient NMR.
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<br /> 9.3.1.3 Electrochemical Determination of Diffusion
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<br /> Coefficients.
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<br /> 9.3.2 Measurement of the Transport of Charged Species Only.
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<br /> 9.3.2.1 Hittorf/Tubandt Method.
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<br /> 9.3.2.2 Concentration Cell Techniques.
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<br /> 9.3.2.3 Cells in Force Fields.
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<br /> 9.3.3 Transport under a Chemical Potential and Electrical Gradient.
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<br /> 9.3.3.1 Alternating–Current Impedance.
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<br /> 9.3.3.2 Direct–Current Polarization Methods.
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<br /> Fully Dissociated Electrolytes.
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<br /> Systems Containing Mobile Ion Pairs.
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<br /> Systems Containing Triple Ions.
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<br /> References.
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<br /> Chapter 10. The Electrode–Electrolyte Interface.
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<br /> 10.1 The Lithium–Polymer Electrolyte Interface.
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<br /> 10.2 Electrochemical Stability.
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<br /> 10.3 Intercalation.
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<br /> 10.4 Electrochromism of Intercalation Compounds.
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<br /> References.
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<br /> Index.